|Publisher DOI:||10.1016/j.polymer.2022.125365||Title:||Electroactive performance and cost evaluation of carbon nanotubes and carbon black as conductive fillers in self-healing shape memory polymers and other composites||Language:||English||Authors:||Orozco, Felipe
Ribas Gomes, Diego
Araya-Hermosilla, Esteban Alejandro
Bose, Ranjita K.
|Keywords:||Cost-performance analysis; Electrical properties; Microstructural analysis; Polymer-matrix composites (PMCs)||Issue Date:||23-Sep-2022||Publisher:||Elsevier Science||Source:||Polymer 260 (): 125365 (2022)||Abstract (english):||
Multiwalled carbon nanotubes (MWCNT) and carbon black (CB) have been widely used as conductive fillers in electroactive polymer composites. MWCNT-based composites generally have lower resistivity and percolation thresholds, while CB-based ones are considerably cheaper. To balance these pros and cons, ternary composites (TCs) (polymer-MWCNT-CB) can be formulated. Here, we prepared electroactive MWCNT-CB TCs capable of self-healing and with shape memory properties, based on polyketones reversibly-crosslinked via Diels-Alder chemistry. Unexpectedly, the cheaper CB-rich formulations had lower resistivities, thus better electroactive self-healing and shape memory responses. Nonetheless, not all electroactive MWCNT-CB TCs have this clear cost-effectiveness. We evaluated the cost-performance of multiple reported MWCNT-CB TCs systems and found different general trends (positive, negative, and synergistic cost-efficiency relationships). Thus, the cost-effectiveness of these fillers (and their combination) greatly depends on each composite system and what it is intended for. This work includes the first systematic report on cost-performance of MWCNT and CB as conductive fillers.
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