Please use this identifier to cite or link to this item: https://doi.org/10.15480/882.1927
Publisher DOI: 10.1016/j.jcis.2017.07.085
Title: Influence of carbon nanoparticle modification on the mechanical and electrical properties of epoxy in small volumes
Language: English
Authors: Leopold, Christian  
Augustin, Till  
Schwebler, Thomas 
Lehmann, Jonas 
Liebig, Wilfried V.  
Fiedler, Bodo 
Keywords: damage mechanisms;fractography;percolation behaviour;sensing;structural health monitoring;true failure strength;damage mechanism
Issue Date: 25-Jul-2017
Publisher: Elsevier
Source: Journal of colloid and interface science (506): 620-632 (2017)
Journal or Series Name: Journal of colloid and interface science 
Abstract (english): The influence of nanoparticle morphology and filler content on the mechanical and electrical properties of carbon nanoparticle modified epoxy is investigated regarding small volumes. Three types of particles, representing spherical, tubular and layered morphologies are used. A clear size effect of increasing true failure strength with decreasing volume is found for neat and carbon black modified epoxy. Carbon nanotube (CNT) modified epoxy exhibits high potential for strength increase, but dispersion and purity are critical. In few layer graphene modified epoxy, particles are larger than statistically distributed defects and initiate cracks, counteracting any size effect. Different toughness increasing mechanisms on the nano- and micro-scale depending on particle morphology are discussed based on scanning electron microscopy images. Electrical percolation thresholds in the small volume fibres are significantly higher compared to bulk volume, with CNT being found to be the most suitable morphology to form electrical conductive paths. Good correlation between electrical resistance change and stress strain behaviour under tensile loads is observed. The results show the possibility to detect internal damage in small volumes by measuring electrical resistance and therefore indicate to the high potential for using CNT modified polymers in fibre reinforced plastics as a multifunctional, self-monitoring material with improved mechanical properties.
URI: http://tubdok.tub.tuhh.de/handle/11420/1930
DOI: 10.15480/882.1927
ISSN: 1095-7103
Institute: Kunststoffe und Verbundwerkstoffe M-11 
Type: (wissenschaftlicher) Artikel
License: CC BY 4.0 (Attribution) CC BY 4.0 (Attribution)
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