Publisher DOI: 10.1002/aic.15598
Title: Enzymatic catalyzed reactive dividing wall column: experiments and model validation
Language: English
Authors: Egger, Torben 
Fieg, Georg 
Keywords: distillation;enzymes;simulation;mathematical modeling;reactive dividing wall column
Issue Date: 21-Dec-2016
Publisher: American Institute of Chemical Engineers
Source: AIChE Journal 6 (63): 2198-2211 (2017-06-01)
Journal or Series Name: AIChE journal 
Abstract (english): A novel process for the integration of chemical reaction and product separation is proposed: the enzymatic catalyzed reactive dividing wall column (eRDWC). The eRDWC combines the highly integrated and complex reactive dividing wall column (RDWC) with the use of a very selective enzymatic catalyst. This apparatus enables the simultaneous production and separation of up to 4 pure product streams. Comprehensive experiments with the reference system of a hexanol and butyl acetate transesterification in a DN 65 pilot scale column show the feasibility of stable steady state operations for this process. A rigorous model for the plant design of an eRDWC wall column is developed. The reaction kinetics and vapor-liquid-equilibria for the reference system are measured and implemented in the model. The model is successfully validated using the acquired experimental data. The application of enzymes in continuous reactive distillation processes has the potential to increase the selectivity at milder process conditions. © 2016 American Institute of Chemical Engineers AIChE J, 63: 2198–2211, 2017.
URI: http://hdl.handle.net/11420/3181
ISSN: 1547-5905
Institute: Prozess- und Anlagentechnik V-4 
Type: (wissenschaftlicher) Artikel
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