Waltermann, ThomasThomasWaltermannSchlueter, StefanStefanSchlueterBenfer, ReginaReginaBenferKnoesche, CarstenCarstenKnoescheGórak, AndrzejAndrzejGórakSkiborowski, MirkoMirkoSkiborowski2020-11-232020-11-232020-07-01Chemie-Ingenieur-Technik 7 (92): 890-906 (2020-07-01)http://hdl.handle.net/11420/7902While rate-based models are available in commercial flowsheet simulation tools, packed distillation columns are still mostly designed based on the equilibrium stage model in combination with HETP values. In order to discriminate between both types of models in a simple way, this article proposes an algorithmic test, based on a geometric criterion for total reflux operation. Substantial differences are illustrated especially for wide-boiling mixtures, while component-specific mass transfer rates either increase or reduce the deviation. The derived results are validated by dedicated experiments.en0009-286X20207890906DistillationEquilibrium stage modelModel discriminationRate-based modelJournal Article10.1002/cite.202000026Other