Che, JunweiJunweiCheLiu, XiangyangXiangyangLiuWang, XuezhiXuezhiWangPagnan Furlan, KalineKalinePagnan FurlanZhang, ShengliShengliZhang2022-12-122022-12-122023-04-01Ceramics International 49 (7): 10936-10945 (2023-04-01)http://hdl.handle.net/11420/14332Pyrochlore-type La₂Zr₂O₇ (LZ) is a promising candidate for high-temperature thermal barrier coatings (TBCs). However, its thermal expansion coefficient and low fracture toughness are not optimal for such application and thus, need to be improved. In this study, we systematically report the effect of CeO2 addition on phase formation, oxygen-ion diffusion, and thermophysical and mechanical properties of full compositions La₂(Zr₁−xCex)₂O₇ (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1). La₂(Zr₁−xCex)₂O₇ exhibits a pyrochlore structure at x ≤ 0.3, while a fluorite structure is observed outside this range. With the increase in CeO2 content, thermal expansion coefficient and oxygen-ion diffusivity in La₂(Zr₁−xCex)₂O₇ are increased. Oxygen-ion diffusivity of La₂(Zr₁−xCex)₂O₇ is two orders of magnitude less than that of classical 8YSZ. Among La₂(Zr₁−xCex)₂O₇ compounds, La₂(Zr0.7Ce0.3)₂O₇ and La₂(Zr0.5Ce0.5)₂O₇ exhibit relatively low oxygen diffusivities. The composition La₂(Zr0.5Ce0.5)₂O₇ presents the lowest thermal conductivity due to the strongest phonon scattering and also the highest fracture toughness due to the solid-solution toughening. The highest sintering resistance is achieved by the composition La₂(Zr0.7Ce0.3)₂O₇ because of its ordered pyrochlore structure and high atomic mass of Ce. Based on these results, the compositions La₂(Zr0.5Ce0.5)₂O₇ and La₂(Zr0.7Ce0.3)₂O₇ are alternatives for classical 8YSZ for TBC materials operating at ultrahigh temperatures.en0272-8842202371093610945La (Zr − Ce ) O 2 1 x x 2 7Mechanical propertiesOxygen-ion diffusivityThermal barrier coatingsThermophysical propertiesJournal Article10.1016/j.ceramint.2022.11.288Journal Article