Wolff, MatthiasMatthiasWolffKruchten, FrankFrankKruchtenHuber, PatrickPatrickHuberKnorr, KlausKlausKnorrVolkmann, Ulrich G.Ulrich G.Volkmann2022-06-072022-06-072011-04-13Physical Review Letters 106 (15): 156103 (2011-04-17)http://hdl.handle.net/11420/12819Multilayer sorption isotherms of 1-propanol on graphite have been measured by means of high-resolution ellipsometry within the liquid regime of the adsorbed film for temperatures ranging from 180 to 260 K. In the first three monolayers the molecules are oriented parallel to the substrate and the growth is roughly consistent with the Frenkel-Halsey-Hill-model (FHH) that is obeyed in van-der-Waals systems on strong substrates. The condensation of the fourth and higher layers is delayed with respect to the FHH-model. The fourth layer is actually a bilayer. Furthermore there is indication of a wetting transition. The results are interpreted in terms of hydrogen-bridge bonding within and between the layers.en1079-7114201115American Physical SocietyPhysics - Chemical PhysicsPhysics - Chemical PhysicsPhysics - Mesoscopic Systems and Quantum Hall EffectPhysics - Materials SciencePhysics - Soft Condensed MatterPhysikJournal Article10.1103/PhysRevLett.106.1561031104.3319v1Other