Vega Mercado, F.F.Vega MercadoOvejero, J. M.J. M.OvejeroZanotto, Franco MartínFranco MartínZanottoSerial, Maria RaquelMaria RaquelSerialVelasco, Manuel IsaacManuel IsaacVelascoFernández, R. A.R. A.FernándezAcosta, Rodolfo HectorRodolfo HectorAcostaDassie, Sergio AlbertoSergio AlbertoDassie2021-07-132021-07-132017Journal of Electroanalytical Chemistry 791: 64-74-74 (2017)http://hdl.handle.net/11420/9882A novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach is based on the measurement of the total transferred charge across the oil | water interface under forced hydrodynamic conditions. The complete procedure has been validated by computational simulations and experimental results (Tylosin A). In addition, flow pattern caused inside the electrochemical cell was simulated with computational fluid dynamics using finite element methods and correlated with experimental results obtained by magnetic resonance imaging.en1572-6657Journal of electroanalytical chemistry201764-7474Facilitated proton transferFinite element methodForced hydrodynamic conditionsLiquid liquid interfaceMagnetic resonance imagingPartition coefficientFacilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak basesJournal Article10.1016/j.jelechem.2017.03.005Journal Article