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Enhancing swelling kinetics of pNIPAM lyogels: The role of crosslinking, copolymerization, and solvent
Citation Link: https://doi.org/10.15480/882.15168
Publikationstyp
Journal Article
Date Issued
2025-10-01
Sprache
English
Author(s)
TORE-DOI
Journal
Volume
597
Article Number
114462
Citation
Fluid Phase Equilibria 597: 114462 (2025)
Publisher DOI
Scopus ID
Publisher
Elsevier
Stimuli-responsive lyogels are known for their ability to undergo significant macroscopic changes when exposed to external stimuli. While thermo-responsive gels, such as poly-N-isopropylacrylamide (pNIPAM), have been extensively studied across various applications, solvent-induced swelling has predominantly been investigated in aqueous solutions. This study explores the tailoring of lyogel formulations for future applications by controlling their solvent-induced swelling behavior, comparing both homopolymeric and semi-interpenetrating polymer networks (semi-IPNs). It is structured in two parts: the first focuses on characterization techniques, including NMR relaxometry, swelling degree measurements, mechanical testing, and SEM analysis, while the second part delves into swelling kinetic analysis, applying solvent exchange as a stimulus for varying gel formulations and solvents. In contrast to most previous studies, the impact of chemical and physical crosslinking, as well as copolymer inclusion, on the swelling behavior and mechanical properties of lyogels in organic solvents is examined and compared with solvent-induced swelling kinetics measurements. The results demonstrate that increasing chemically crosslinking in homopolymers and physically crosslinking in semi-IPNs enhances mechanical stability, while improving mass transport properties and solvent exchange kinetics. However, increases degree of crosslinking results in a prolonged response time to the solvent exchange stimulus and a reduction in the overall swelling capacity of the lyogels. Furthermore, variations in solvent properties, including molecular size and diffusion rates, significantly influence the swelling kinetics, whereas smaller, faster-diffusing solvents leading to more pronounced solvent spillage effects. Our findings highlight the complex interplay between gel formulation, network structure, and solvent nature in determining the solvent-induced swelling kinetics of lyogels, providing insights into how these materials can be tailored for specific applications especially those requiring short response times and optimized mechanical properties.
Subjects
Polymer | Semi-IPN | Smart reactors | Solvent-induced | Stimuli-responsive gels | Swelling kinetics
DDC Class
541: Physical; Theoretical
620.1: Engineering Mechanics and Materials Science
660: Chemistry; Chemical Engineering
More Funding Information
This project is funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – SFB 1615 – 503850735.
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