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One‐step formation of hybrid nanocrystal gels: Deposition of metal domains on CdSe/CdS nanorod and nanoplatelet networks
Publikationstyp
Journal Article
Date Issued
2021-05-29
Sprache
English
Author(s)
Zámbó, Dániel
Schlosser, Anja
Graf, Rebecca T.
Rusch, Pascal
Bigall, Nadja C.
Journal
Volume
9
Issue
17
Citation
Advanced optical materials 9 (17): (2021-05-29)
Publisher DOI
Scopus ID
Publisher
Wiley
Hybrid semiconductor‐based nanocrystals (NCs) are generally synthesized in organic media prior to their assembly into catalytically promising nanostructures via multistep methods. Here, a tunable, easy‐to‐adapt and versatile approach for the preparation of hybrid nanoparticle networks from aqueous nanocrystal solutions is demonstrated. The networks consist of interconnected semiconductor NC backbones (made of CdSe/CdS dot‐in‐rods or core/crown nanoplatelets) decorated with noble metal (Au and Pt) or with metal‐based domains (Co2+ and Ni2+) demonstrating a powerful synthetic control over a variety of hybrid nanostructures. The deposition of the domains and the formation of the network take place simultaneously (one‐step method) at room temperature in dark conditions without any external trigger. Beside the in‐depth structural characterization of the gel‐like hybrid networks, the wavelength‐dependent optical features are studied to reveal an efficient charge carrier separation in the systems and a controllable extent of fluorescence quenching through the domain sizes. Photoluminescence quantum yields and decay dynamics highlight the importance of fine‐tuning the conduction band/Fermi level offset between the semiconductors and the various deposited metals playing central role in the electron–hole separation processes. This procedure provides a novel platform toward the preparation of photo(electro)catalytically promising hybrid nanostructures (acetogels and xerogels) without the need of presynthetic hybrid particle design.
Subjects
charge carrier separation
gel networks
hybrid nanostructures
metal domain
semiconductor nanoplatelets
semiconductor nanorods
DDC Class
540: Chemistry