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Nucleation and growth of copper on mesoporous silicon by immersion plating
Publikationstyp
Journal Article
Date Issued
2007-05-07
Sprache
English
Author(s)
Volume
40
Issue
9
Start Page
2864
End Page
2869
Article Number
030
Citation
Journal of Physics D: Applied Physics 40 (9): 030 2864-2869 (2007-05-07)
Publisher DOI
Scopus ID
Publisher
IOP Publ.
Copper deposition was investigated on electrochemically etched mesoporous silicon epilayers of pore diameter 7 nm, porosity 45% and surface area 500 m2 cm-3 by immersion plating in an aqueous solution containing Cu2+ ions. When the layers were immersed in a 0.1 M CuSO4 5H2O aqueous solution for different time-periods ranging from 1 to 60 min, elemental copper was deposited on the surface. Fourier transform infrared (FTIR) spectroscopy in transmittance mode was carried out on copper deposited porous silicon (PS) samples to infer the changes in the surface bonding of the PS. It was clearly observed from x-ray diffraction patterns and FTIR spectra that the reduction of copper ion on PS was accompanied by gradual and finally complete oxidation of the PS epilayers surface. Scanning electron microscopy has been used to study the morphology of the copper aggregates at the PS epilayers surface.
DDC Class
530: Physik