Engineered self-assembly of plasmonic gold nanoparticles into two-dimensional and three-dimensional arrays within the pores of porous silicon membranes

We report a facile centrifugation-based method for assembling polystyrene (PSSH)-functionalized gold nanoparticles (Au NPs) onto porous silicon (pSi) substrates in two distinct configurations: two- and three-dimensional (2D and 3D) assemblies. The 2D assemblies are densely packed monolayer coatings of the exposed Si-surfaces including the inner pore walls, whereas the 3D structures result from Au NPs clustering inside the pores. Remarkably, this shift from 2D to 3D architectures was achieved by minor modification of the PSSH coating thickness. Scanning electron microscopy (SEM) characterization confirmed the homogeneity and high packing density of these assemblies extending over several thousand square micrometers. This approach offers a straightforward and versatile route for the fabrication of well-ordered pSi–Au NP hybrid nanostructures with potential applications in catalysis, surface-enhanced spectroscopy and optical metamaterials.

Subjects

gold nanoparticles

nanofabrication

nanomaterials

porous silicon

surface-enhanced Raman spectroscopy

DDC Class

530: Physics

540: Chemistry

660: Chemistry; Chemical Engineering

Lizenz

https://creativecommons.org/licenses/by/4.0/

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publishedVersion

Name

ChemNanoMat - 2026 - Barrios‐Capuchino - Engineered Self‐Assembly of Plasmonic Gold Nanoparticles Into Two‐Dimensional and.pdf

Type

Main Article

Size

3.07 MB

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Adobe PDF

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Engineered self-assembly of plasmonic gold nanoparticles into two-dimensional and three-dimensional arrays within the pores of porous silicon membranes