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Biosorption of neodymium on Chlorella vulgaris in aqueous solution obtained from hard disk drive magnets
Citation Link: https://doi.org/10.15480/882.1984
Publikationstyp
Journal Article
Date Issued
2017-04-07
Sprache
English
TORE-DOI
Journal
Volume
12
Issue
4
Start Page
e0175255
Citation
PLoS ONE 4 (12): e0175255 (2017)
Publisher DOI
Scopus ID
Publisher
Public Library of Science (PLos)
In recent years, biosorption is being considered as an environmental friendly technology for the recovery of rare earth metals (REE). This study investigates the optimal conditions for the biosorption of neodymium (Nd) from an aqueous solution derived from hard drive disk magnets using green microalgae (Chlorella vulgaris). The parameters considered include solution pH, temperature and biosorbent dosage. Best-fit equilibrium as well as kinetic biosorption models were also developed. At the optimal pH of 5, the maximum experimental Nd uptakes at 21, 35 and 50°C and an initial Nd concentration of 250 mg/L were 126.13, 157.40 and 77.10 mg/g, respectively. Analysis of the optimal equilibrium sorption data showed that the data fitted well (R2= 0.98) to the Langmuir isotherm model, with maximum monolayer coverage capacity (qmax) of 188.68 mg/g, and Langmuir isotherm constant (KL) of 0.029 L/mg. The corresponding separation factor (RL) is 0.12 indicating that the equilibrium sorption was favorable. The sorption kinetics of Nd ion follows well a pseudo-second order model (R2>0.99), even at low initial concentrations. These results show that Chlorella vulgaris has greater biosorption affinity for Nd than activated carbon and other algae types such as: A. Gracilis, Sargassum sp. and A. Densus.
Subjects
kinetic biosorption models
DDC Class
570: Biowissenschaften, Biologie
More Funding Information
Bundesministerium für Bildung und Forschung
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journal.pone.0175255.pdf
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