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Ionic liquid dynamics in nanoporous carbon : a pore-size- and temperature-dependent neutron spectroscopy study on supercapacitor materials
Citation Link: https://doi.org/10.15480/882.2964
Publikationstyp
Journal Article
Date Issued
2020-05-06
Sprache
English
TORE-DOI
TORE-URI
Journal
Volume
4
Issue
5
Start Page
055401-1
End Page
055401-12
Article Number
055401
Citation
Phys. Rev. Materials 4 (5): 055401 (2020-05-05)
Publisher DOI
Scopus ID
ArXiv ID
Publisher
AIP
The influence of spatial confinement on the thermally excited stochastic cation dynamics of the room-temperature ionic liquid 1-N-butylpyridinium bis-((trifluoromethyl)sulfonyl)imide ([BuPy][Tf₂N]) inside porous carbide-derived carbons with various pore sizes in the sub- to a few nanometer range are investigated by quasi-elastic neutron spectroscopy. Using the potential of fixed window scans, i.e. scanning a sample parameter, while observing solely one specific energy transfer value, an overview of the dynamic landscape within a wide temperature range is obtained. It is shown that already these data provide a quite comprehensive understanding of the confinement-induced alteration of the molecular mobility in comparison to the bulk. A complementary, more detailed analysis of full energy transfer spectra at selected temperatures reveals two translational diffusive processes on different time scales. Both are considerably slower than in the bulk liquid and show a decrease of the respective self-diffusion coefficients with decreasing nanopore size. Different thermal activation energies for molecular self-diffusion in nanoporous carbons with similar pore size indicate the importance of pore morphology on the molecular mobility, beyond the pure degree of confinement. In spite of the dynamic slowing down we can show that the temperature range of the liquid state upon nanoconfinement is remarkably extended to much lower temperatures, which is beneficial for potential technical applications of such systems.
Subjects
Materials Science
Soft Condensed Matter
Quasi-elastic neutron scattering
ionic liquids
carbide-derived carbons
nanoporous carbon
self-diffusion dynamics
nanoconfinement
DDC Class
530: Physik
Publication version
publishedVersion
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