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  4. Responsive Mn‐ferrite nanoparticles for multicolor magnetic particle imaging, sensing, and reactive oxygen species degradation
 
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Responsive Mn‐ferrite nanoparticles for multicolor magnetic particle imaging, sensing, and reactive oxygen species degradation

Citation Link: https://doi.org/10.15480/882.16089
Publikationstyp
Journal Article
Date Issued
2025-04-28
Author(s)
Starsich, Fabian H. L.
Feye, Julia
Niβler, Robert
Da Silva André Gabriela  
Totter, Elena  
Scheffler, Konrad  
Biomedizinische Bildgebung E-5  
Thieben, Florian  orcid-logo
Biomedizinische Bildgebung E-5  
Mayr, Erik
Franke, Jochen
Knopp, Tobias  
Biomedizinische Bildgebung E-5  
Herrmann, Inge K.  
TORE-DOI
10.15480/882.16089
TORE-URI
https://hdl.handle.net/11420/58466
Journal
Advanced sensor research  
Volume
4
Issue
6
Article Number
2400189
Citation
Advanced sensor research 4 (6): 2400189 (2025)
Publisher DOI
10.1002/adsr.202400189
Publisher
Wiley
New possibilities offered by Magnetic Particle Spectroscopy (MPS) and Imaging (MPI) are increasingly being recognized and may accelerate the introduction of MPI into clinical settings. As MPI is a tracer-based imaging method, the design and development of responsive tracers for functional imaging are particularly appealing. Here, Mn-ferrite (MnxFe3-xO4)
nanoparticles with finely tuned magnetic properties and enzyme-like capabilities are reported as potential multifunctional theranostic agents. By adjusting the Mn content in the iron oxide matrix, the magnetic particle imaging signal of different tracers can be tweaked, allowing for the simultaneous quantitative detection of two different tracers in a multi-color
approach. The Mn2FeO4 tracers exhibit potent enzyme-like catalytic properties, enabling degradation of reactive oxygen species, including H2O2 and OH−. Due to the readily interchangeable oxidation states of Mn and Fe atoms in the crystal structure, a strong dependence of the magnetic properties is observed on H2O2 exposure, which can be exploited for sensing. This enables, for the first time, the sensing of reactive oxygen species based on magnetic particle spectroscopy and imaging, with sensitivity down to 25 μmH2O2 and complete sensor recovery over time. In summary, Mn-ferrite nanoparticles hold promising potential for imaging, sensing, and degradation of disease-relevant reactive oxygen species.
Subjects
magnetic particle spectroscopy
nanozyme
sensor
theranostics
tissue injury
DDC Class
570: Life Sciences, Biology
610: Medicine, Health
Publication version
publishedVersion
Lizenz
https://creativecommons.org/licenses/by/4.0/
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