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  4. Influence of Pore Surface Chemistry on the Rotational Dynamics of Nanoconfined Water
 
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Influence of Pore Surface Chemistry on the Rotational Dynamics of Nanoconfined Water

Publikationstyp
Journal Article
Date Issued
2021-07-27
Sprache
English
Author(s)
Malfait, Benjamin  
Jani, Aicha  
Mietner, Jakob Benedikt  
Lefort, Ronan  
Huber, Patrick  orcid-logo
Fröba, Michael  
Morineau, Denis  
Institut
Material- und Röntgenphysik M-2  
TORE-URI
http://hdl.handle.net/11420/10291
Journal
The journal of physical chemistry C  
Volume
125
Issue
30
Start Page
16864
End Page
16874
Citation
Journal of Physical Chemistry C 125 (30): 16864-16874 (2021-07-27)
Publisher DOI
10.1021/acs.jpcc.1c05502
Scopus ID
2-s2.0-85112536991
ArXiv ID
2107.12798v1
We have investigated the dynamics of water confined in mesostructured porous silicas (SBA-15, MCM-41) and four periodic mesoporous organosilicas (PMOs) by dielectric relaxation spectroscopy. The influence of water-surface interaction has been controlled by the carefully designed surface chemistry of PMOs that involved organic bridges connecting silica moieties with different repetition lengths, hydrophilicity and H-bonding capability. Relaxation processes attributed to the rotational motions of non-freezable water located in the vicinity of the pore surface were studied in the temperature range from 140 K to 225 K. Two distinct situations were achieved depending on the hydration level: at low relative humidity (33% RH), water formed a non-freezable layer adsorbed on the pore surface. At 75% RH, water formed an interfacial liquid layer sandwiched between the pore surface and the ice crystallized in the pore center. In the two cases, the study revealed different water dynamics and different dependence on the surface chemistry. We infer that these findings illustrate the respective importance of water-water and water-surface interactions in determining the dynamics of the interfacial liquid-like water and the adsorbed water molecules, as well as the nature of the different H-bonding sites present on the pore surface.
Subjects
Physics - Soft Condensed Matter
Physics - Soft Condensed Matter
Physics - Chemical Physics
Funding(s)
Veränderung der Eigenschaften mehrphasiger Flüssigkeiten durch geometrische Beschränkung in modernen mesoporösen Materialien  
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