TUHH Open Research
Help
  • Log In
    New user? Click here to register.Have you forgotten your password?
  • English
  • Deutsch
  • Communities & Collections
  • Publications
  • Research Data
  • People
  • Institutions
  • Projects
  • Statistics
  1. Home
  2. TUHH
  3. Publications
  4. Hydrophobic Modification of Biopolymer Aerogels by Cold Plasma Coating
 
Options

Hydrophobic Modification of Biopolymer Aerogels by Cold Plasma Coating

Citation Link: https://doi.org/10.15480/882.3768
Publikationstyp
Journal Article
Date Issued
2021-09-04
Sprache
English
Author(s)
Schroeter, Baldur  orcid-logo
Jung, Isabella  
Bauer, Katharina  
Gurikov, Pavel  
Smirnova, Irina  orcid-logo
Institut
Thermische Verfahrenstechnik V-8  
TORE-DOI
10.15480/882.3768
TORE-URI
http://hdl.handle.net/11420/10328
Journal
Polymers  
Volume
13
Issue
17
Article Number
3000
Citation
Polymers 13 (17): 3000 (2021)
Publisher DOI
10.3390/polym13173000
Scopus ID
2-s2.0-85114483033
Publisher
Multidisciplinary Digital Publishing Institute
The aim of this work was to evaluate the potential of cold plasma polymerization as a simple, fast and versatile technique for deposition of protective hydrophobic and oleophobic polymer layers on hydrophilic biopolymer aerogels. Polymerization of different fluorinated monomers (octafluorocyclobutane C<sub>4</sub>F<sub>8</sub> and perfluoro-acrylates PFAC-6 and PFAC-8) on aerogel monoliths derived from alginate, cellulose, whey protein isolate (WPI) and potato protein isolate (PPI) resulted in fast and significant surface hydrophobization after short process times of 5 min and led to superhydrophobic surfaces with static water contact angles up to 154° after application of poly-C<sub>4</sub>F<sub>8</sub> coatings. Simultaneous introduction of hydro- and oleophobicity was possible by deposition of perfluoro-acrylates. While the porous structure of aerogels stayed intact during the process, polymerization inside the aerogels pores led to the generation of new porous moieties and resulted therefore in significant increase in the specific surface area. The magnitude of the effect depended on the individual process settings and on the overall porosity of the substrates. A maximization of specific surface area increase (+179 m<sup>2</sup>/g) was obtained by applying a pulsed wave mode in the C<sub>4</sub>F<sub>8</sub>-coating of alginate aerogels.
DDC Class
600: Technik
Funding(s)
Publikationsfonds 2021  
Publication version
publishedVersion
Lizenz
https://creativecommons.org/licenses/by/4.0/
Loading...
Thumbnail Image
Name

polymers-13-03000-v2.pdf

Size

15.42 MB

Format

Adobe PDF

TUHH
Weiterführende Links
  • Contact
  • Send Feedback
  • Cookie settings
  • Privacy policy
  • Impress
DSpace Software

Built with DSpace-CRIS software - Extension maintained and optimized by 4Science
Design by effective webwork GmbH

  • Deutsche NationalbibliothekDeutsche Nationalbibliothek
  • ORCiD Member OrganizationORCiD Member Organization
  • DataCiteDataCite
  • Re3DataRe3Data
  • OpenDOAROpenDOAR
  • OpenAireOpenAire
  • BASE Bielefeld Academic Search EngineBASE Bielefeld Academic Search Engine
Feedback