Entwicklung einer chemoenzymatischen Reaktionssequenz zur Synthese von Fettalkoholen

Publikationstyp
Doctoral Thesis
Date Issued
2022
Sprache
German
Author(s)
Naße, Kim Elisabeth  
Advisor
Liese, Andreas  orcid-logo
Referee
Gröger, Harald  
Title Granting Institution
Technische Universität Hamburg
Place of Title Granting Institution
Hamburg
Examination Date
2021-07-22
Institut
Technische Biokatalyse V-6  
TORE-DOI
10.15480/882.4107
TORE-URI
http://hdl.handle.net/11420/11519
Citation
Technische Universität Hamburg (2022)
Fatty alcohols are important chemical intermediates and are mainly applied as emulsifiers, surfactants and lubricants. Therefore, an efficient and sustainable synthesis is necessary. A chemoenzymatic approach was employed to develop a solvent-free and almost completely atom-economical reaction sequence. Besides the two catalysts, no further substances are necessary in order to combine the esterification of a fatty alcohol with the corresponding fatty acid and the subsequent hydrogenation of the formed wax ester. Based on this idea, two process variants were realized, as well as the development of a catalyst recycling concept.
DDC Class
660: Technische Chemie
Lizenz
http://rightsstatements.org/vocab/InC/1.0/
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