Please use this identifier to cite or link to this item: https://doi.org/10.15480/882.1625
DC FieldValueLanguage
dc.contributor.authorWittenberg, Elisabeth-
dc.contributor.authorMeyer, Andreas-
dc.contributor.authorEggers, Steffen-
dc.contributor.authorAbetz, Volker-
dc.date.accessioned2018-04-19T08:53:18Z-
dc.date.available2018-04-19T08:53:18Z-
dc.date.issued2018-04-04-
dc.identifier.citationSoft matter 14 (14): 2701-2711 (2018-04-04)de_DE
dc.identifier.issn1744-683Xde_DE
dc.identifier.urihttp://tubdok.tub.tuhh.de/handle/11420/1628-
dc.description.abstractStyrene-butadiene copolymers are modified with varying fractions of benzoic acid moieties being able to perform hydrogen bonding. This is done by using a simple synthetic approach which utilizes click hemistry. Temperature-dependent dynamic mechanical properties are studied, and it turns out that even the apparently rather simple ydrogen bonding motif has a marked impact on the material properties due to the fact that it facilitates the formation of a supramolecular polymer network. Besides a glass transition, the investigated functionalized copolymers exhibit a second endothermic transition, known as a quasi-melting. This is related to the opening of the hydrogen bonding complexes. Additionally to dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), temperature-dependent infrared (IR) spectroscopy and small angle X-ray scattering (SAXS) are used to understand the structure-property relationships.en
dc.language.isoende_DE
dc.relation.ispartofSoft matterde_DE
dc.rightsCC-BY-NCde_DE
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/
dc.subject.ddc620: Ingenieurwissenschaftende_DE
dc.titleHydrogen bonding and thermoplastic elastomers - a nice couple with temperature-adjustable mechanical propertiesde_DE
dc.typeArticlede_DE
dc.identifier.urnurn:nbn:de:gbv:830-88220368-
dc.identifier.doi10.15480/882.1625-
dc.type.diniarticle-
dc.subject.ddccode620-
dcterms.DCMITypeText-
tuhh.identifier.urnurn:nbn:de:gbv:830-88220368de_DE
tuhh.oai.showtrue-
dc.identifier.hdl11420/1628-
tuhh.abstract.englishStyrene-butadiene copolymers are modified with varying fractions of benzoic acid moieties being able to perform hydrogen bonding. This is done by using a simple synthetic approach which utilizes click hemistry. Temperature-dependent dynamic mechanical properties are studied, and it turns out that even the apparently rather simple ydrogen bonding motif has a marked impact on the material properties due to the fact that it facilitates the formation of a supramolecular polymer network. Besides a glass transition, the investigated functionalized copolymers exhibit a second endothermic transition, known as a quasi-melting. This is related to the opening of the hydrogen bonding complexes. Additionally to dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), temperature-dependent infrared (IR) spectroscopy and small angle X-ray scattering (SAXS) are used to understand the structure-property relationships.de_DE
tuhh.publisher.doi10.1039/C8SM00296G-
tuhh.publication.instituteWerkstoffphysik und -technologie M-22de_DE
tuhh.identifier.doi10.15480/882.1625-
tuhh.type.opus(wissenschaftlicher) Artikel-
tuhh.institute.germanWerkstoffphysik und -technologie M-22de
tuhh.institute.englishWerkstoffphysik und -technologie M-22de_DE
tuhh.gvk.hasppnfalse-
tuhh.hasurnfalse-
openaire.rightsinfo:eu-repo/semantics/openAccessde_DE
dc.type.driverarticle-
dc.rights.ccversion3.0de_DE
dc.type.casraiJournal Article-
tuhh.container.issue14de_DE
tuhh.container.startpage2701de_DE
tuhh.container.endpage2711de_DE
dc.rights.nationallicensefalsede_DE
item.grantfulltextopen-
item.creatorGNDWittenberg, Elisabeth-
item.creatorGNDMeyer, Andreas-
item.creatorGNDEggers, Steffen-
item.creatorGNDAbetz, Volker-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.creatorOrcidWittenberg, Elisabeth-
item.creatorOrcidMeyer, Andreas-
item.creatorOrcidEggers, Steffen-
item.creatorOrcidAbetz, Volker-
item.languageiso639-1en-
item.cerifentitytypePublications-
crisitem.author.orcid0000-0002-1181-892X-
crisitem.author.orcid0000-0002-4840-6611-
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