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Chemo-mechanical coupling in nanoporous palladium-hydrogen
Citation Link: https://doi.org/10.15480/882.2093
Publikationstyp
Doctoral Thesis
Date Issued
2019
Sprache
English
Author(s)
Advisor
Referee
Title Granting Institution
Technische Universität Hamburg
Place of Title Granting Institution
Hamburg
Examination Date
2019-02-21
TORE-DOI
TORE-URI
Citation
Technische Universität Hamburg (2019)
This thesis establishes the synthesis of monolithic, uniform nanoporous palladium via a single-step electrochemical dealloying of copper-palladium alloys in sulfuric acid. With this nanoporous palladium material, mechanical responses such as large strain and elasticity variations through electrochemically controlled hydrogen sorption are explored by in-situ dilatometry and in-situ dynamic mechanical analysis. The variation of experimentally measured Young’s modulus of nanoporous palladium with hydrogen content agrees well with prediction by Larché-Cahn open-system elasticity theory.
DDC Class
600: Technik
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