DC FieldValueLanguage
dc.contributor.authorDreyer, Axel-
dc.contributor.authorEckstädt, Katrin-
dc.contributor.authorKoop, Thomas-
dc.contributor.authorJutzi, Peter-
dc.contributor.authorHütten, Andreas-
dc.date.accessioned2020-06-05T11:37:36Z-
dc.date.available2020-06-05T11:37:36Z-
dc.date.issued2016-08-04-
dc.identifier.citationRSC Advances 78 (6): 74061-74066 (2016)de_DE
dc.identifier.issn2046-2069de_DE
dc.identifier.urihttp://hdl.handle.net/11420/6248-
dc.description.abstractParticle formation can occur by way of a classical or non-classical nucleation pathway. We show that during the bottom-up synthesis of cobalt particles the degree of particle surface stabilization determines the formation pathway. Without additives, young cobalt particles are liquid because of the size-dependent melting point depression, and crystallization starts only after growth by coalescence, in accord to a non-classical pathway. Addition of surfactants during synthesis leads to particle surface stabilization and, thus, an elevated melting point such that a crystalline nucleus is formed in a classical pathway.en
dc.language.isoende_DE
dc.publisherRSC Publishingde_DE
dc.relation.ispartofRSC Advancesde_DE
dc.subject.ddc600: Technikde_DE
dc.titleSurface stabilization determines a classical: fersus non-classical nucleation pathway during particle formationde_DE
dc.typeArticlede_DE
dc.type.diniarticle-
dcterms.DCMITypeText-
tuhh.abstract.englishParticle formation can occur by way of a classical or non-classical nucleation pathway. We show that during the bottom-up synthesis of cobalt particles the degree of particle surface stabilization determines the formation pathway. Without additives, young cobalt particles are liquid because of the size-dependent melting point depression, and crystallization starts only after growth by coalescence, in accord to a non-classical pathway. Addition of surfactants during synthesis leads to particle surface stabilization and, thus, an elevated melting point such that a crystalline nucleus is formed in a classical pathway.de_DE
tuhh.publisher.doi10.1039/c6ra13041k-
tuhh.publication.instituteKeramische Hochleistungswerkstoffe M-9de_DE
tuhh.type.opus(wissenschaftlicher) Artikel-
dc.type.driverarticle-
dc.type.casraiJournal Article-
tuhh.container.issue78de_DE
tuhh.container.volume6de_DE
tuhh.container.startpage74061de_DE
tuhh.container.endpage74066de_DE
local.status.inpressfalsede_DE
item.creatorGNDDreyer, Axel-
item.creatorGNDEckstädt, Katrin-
item.creatorGNDKoop, Thomas-
item.creatorGNDJutzi, Peter-
item.creatorGNDHütten, Andreas-
item.openairecristypehttp://purl.org/coar/resource_type/c_6501-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairetypeArticle-
item.cerifentitytypePublications-
item.creatorOrcidDreyer, Axel-
item.creatorOrcidEckstädt, Katrin-
item.creatorOrcidKoop, Thomas-
item.creatorOrcidJutzi, Peter-
item.creatorOrcidHütten, Andreas-
item.fulltextNo Fulltext-
crisitem.author.deptKeramische Hochleistungswerkstoffe M-9-
crisitem.author.orcid0000-0002-7571-3684-
crisitem.author.parentorgStudiendekanat Maschinenbau-
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