Hydrothermal flow-through treatment of wheat-straw: detailed characterization of fixed-bed properties and axial dispersion

Journal
Chemical engineering journal  
Volume
281
Start Page
696
End Page
703
Citation
Chemical Engineering Journal (281): 696-703 (2015-12-01)
Publisher DOI
10.1016/j.cej.2015.06.117
Scopus ID
2-s2.0-84937242936
Publisher
Elsevier
The present study focuses on the hydrothermal flow-through treatment of lignocellulosic biomass in a fixed-bed 3. L reactor. In combination with a sequential enzymatic hydrolysis, this process enables selective separation of the lignocellulose in its major constituents in minimal equipment.The aim of this work was to acquire detailed knowledge on the particle and bed structure, biomass degradation and non-ideal flow effects during the hydrothermal treatment. Correlations between the hemicellulose solubilization progress and changing fixed-bed characteristics were identified. This information is essential for the development of a realistic process model that considers hemicellulose reaction kinetics as well as mass and heat transfer separately.Hydrothermally pretreated wheat straw beds were analyzed using the tracer pulse response method at ambient conditions. Non-ideal flow was modeled by means of the dispersion model. Additionally, the effective porosity could be calculated from the residence time distribution curves. It was shown that the axial dispersion coefficient as well as the effective porosity were constant after 15. min of pretreatment. A linear relationship between the axial dispersion coefficient and the interstitial fluid velocity was found. These results allow simplifying the model by assuming constant values of the corresponding variables. The model can further be used to support the development of biorefinery plants at lab and production scale.
Subjects
Dispersion
Fixed-bed properties
Hydrothermal pretreatment
Lignocellulose
Liquid hot water
Modeling
DDC Class
540: Chemie
600: Technik
More Funding Information
The authors are grateful to the German ‘‘Bundesministerium für Bildung und Forschung’’ (BMBF), Germany for the financial support (031A233) in the context of the German Project cluster BIOREFINERY2021.