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Ultra-thin and ultra-strong organic interphase in nanocomposites with supercrystalline particle arrangement : mechanical behavior identification via multiscale numerical modeling
Citation Link: https://doi.org/10.15480/882.2885
Publikationstyp
Journal Article
Date Issued
2020-09-29
Sprache
English
TORE-DOI
TORE-URI
Volume
198
Article Number
108283
Citation
Composites Science and Technology (198): 108283 (2020)
Publisher DOI
Scopus ID
Publisher
Elsevier
© 2020 The Authors. A key challenge in the development of inorganic-organic nanocomposites is the mechanical behavior identification of the organic phase. For supercrystalline materials, in which the organic phase ranges down to sub-nm areas, the identification of the organic materials' mechanical properties is however experimentally inaccessible. The supercrystalline nanocomposites investigated here are 3D superlattices of self-assembled iron oxide nanoparticles, surface-functionalized with crosslinked oleic acid ligands. They exhibit the highest reported values of Young's modulus, nanohardness and strength for inorganic-organic nanocomposites. A multiscale numerical modeling approach is developed to identify these properties using supercrystalline representative volume elements, in which the nanoparticles are arranged in a face-centered cubic superlattice and the organic phase is modeled as a thin layer interfacing each particle. A Drucker-Prager-type elastoplastic constitutive law with perfectly plastic yielding is identified as being able to describe the supercrystals' response in nanoindentation accurately. As the nanoparticles behave in a purely elastic manner with very high stiffness, the underlying constitutive law of the organic phase is also identified to be Drucker-Prager-type elastoplastic, with a Young's modulus of 13 GPa and a uniaxial tensile yield stress of 900 MPa, remarkably high values for an organic material, and matching well with experimental and DFT-based estimations. Furthermore, a sensitivity study indicates that small configurational changes within the supercrystalline lattice do not significantly alter the overall stiffness behavior. Multiscale numerical modeling is thus proven to be able to identify the nanomechanical properties of supercrystals, and can ultimately be used to tailor these materials' mechanical behavior starting from superlattice considerations.
Subjects
Interphase
Mechanical properties
Multiscale modeling
Nano composites
Sensitivity study
DDC Class
540: Chemie
620: Ingenieurwissenschaften
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