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Precursor film spreading during liquid imbibition in nanoporous photonic crystals
Citation Link: https://doi.org/10.15480/882.3248
Publikationstyp
Journal Article
Date Issued
2020-12-01
Sprache
English
TORE-DOI
TORE-URI
Journal
Volume
125
Issue
23
Article Number
234502
Citation
Physical Review Letters 125 (23): 234502 (2020-12-01)
Publisher DOI
Scopus ID
PubMed ID
33337190
ArXiv ID
When a macroscopic droplet spreads, a thin precursor film of liquid moves ahead of the advancing liquid-solid-vapor contact line. Whereas this phenomenon has been explored extensively for planar solid substrates, its presence in nanostructured geometries has barely been studied so far, despite its importance for many natural and technological fluid transport processes. Here we use porous photonic crystals in silicon to resolve by light interferometry capillarity-driven spreading of liquid fronts in pores of few nanometers in radius. Upon spatiotemporal rescaling the fluid profiles collapse on master curves indicating that all imbibition fronts follow a square-root-of-time broadening dynamics. For the simple liquid (glycerol) a sharp front with a widening typical of Lucas-Washburn capillary-rise dynamics in a medium with pore-size distribution occurs. By contrast, for a polymer (PDMS) a precursor film moving ahead of the main menisci entirely alters the nature of the nanoscale transport, in agreement with predictions of computer simulations.
Subjects
Physics - Soft Condensed Matter
Physics - Soft Condensed Matter
Physics - Fluid Dynamics
Physics - Optics
DDC Class
600: Technik
Funding(s)
Publication version
publishedVersion
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Name
PhysRevLett.125.234502.pdf
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1.93 MB
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