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  4. Defects and plasticity in ultrastrong supercrystalline nanocomposites
 
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Defects and plasticity in ultrastrong supercrystalline nanocomposites

Citation Link: https://doi.org/10.15480/882.3260
Publikationstyp
Journal Article
Date Issued
2021-01-06
Sprache
English
Author(s)
Giuntini, Diletta  
Zhao, Shiteng  
Krekeler, Tobias  
Li, Mingjing  
Blankenburg, Malte  
Bor, Büsra  
Schaan, Gunnar  
Domènech Garcia, Berta  
Müller, Martin  
Scheider, Ingo  
Ritter, Martin  orcid-logo
Schneider, Gerold A.  
Institut
Keramische Hochleistungswerkstoffe M-9  
Betriebseinheit Elektronenmikroskopie M-26  
TORE-DOI
10.15480/882.3260
TORE-URI
http://hdl.handle.net/11420/8494
Journal
Science advances  
Volume
7
Issue
2
Article Number
eabb6063
Citation
Science Advances 2 (7): eabb6063 (2021-01-06)
Publisher DOI
10.1126/sciadv.abb6063
Scopus ID
2-s2.0-85099118043
Supercrystalline nanocomposites are nanoarchitected materials with a growing range of applications but unexplored in their structural behavior. They typically consist of organically functionalized inorganic nanoparticles arranged into periodic structures analogous to crystalline lattices, including superlattice imperfections induced by processing or mechanical loading. Although featuring a variety of promising functional properties, their lack of mechanical robustness and unknown deformation mechanisms hamper their implementation into devices. We show that supercrystalline materials react to indentation with the same deformation patterns encountered in single crystals. Supercrystals accommodate plastic deformation in the form of pile-ups, dislocations, and slip bands. These phenomena occur, at least partially, also after cross-linking of the organic ligands, which leads to a multifold strengthening of the nanocomposites. The classic shear theories of crystalline materials are found to describe well the behavior of supercrystalline nanocomposites, which result to feature an elastoplastic behavior, accompanied by compaction.
DDC Class
600: Technik
Funding(s)
SFB 986: Teilprojekt A6 - Herstellung und Charakterisierung hierarchischer, multi-funktionaler Keramik/Metall-Polymer Materialsysteme  
More Funding Information
We acknowledge financial support from the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation), project number 192346071-SFB 986. D.G. acknowledges the support from the Alexander von Humboldt Foundation. B.B. acknowledges the support from the Ministry of National Education of the Republic of Turkey.
Publication version
publishedVersion
Lizenz
https://creativecommons.org/licenses/by-nc/4.0/
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