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  4. Imaging of copper oxygenation reactions in a bubble flow
 
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Imaging of copper oxygenation reactions in a bubble flow

Publikationstyp
Journal Article
Date Issued
2018-09
Sprache
English
Author(s)
Benders, Stefan  
Strassl, Florian  
Fenger, Bastian  
Blümich, Bernhard  
Herres-Pawlis, Sonja  
Küppers, Markus  
TORE-URI
http://hdl.handle.net/11420/8649
Journal
Magnetic resonance in chemistry  
Volume
56
Issue
9
Start Page
826
End Page
830
Citation
Magnetic Resonance in Chemistry 9 (56): 826-830 (2018-09)
Publisher DOI
10.1002/mrc.4742
Scopus ID
2-s2.0-85047661704
PubMed ID
29682795
Reactions of gases with liquids play a crucial role in the production of many bulk chemicals. Often, the gas is bubbled into the chosen reactor. Most of the processes at the gas–liquid interface of the bubbles and in their tails are not fully understood and warrant further investigation. For this purpose, NMR imaging or Magnetic Resonance Imaging has been applied to visualize some of the processes in the bubble tail. To generate sufficient contrast, a magnetogenic gas–liquid reaction associated with a change of magnetic state, from diamagnetic to paramagnetic, was employed. In this work, a copper(I)-based compound was oxidized to copper(II) to exploit relaxation contrast. To match the speed of the rising bubbles to the acquisition time of the spin-echo imaging sequence, polyethylene glycol was added to increase the viscosity of the reacting solution. Images of the oxygen ingress into a static solution as well as of oxygen bubbles rising in the solution are presented. In both cases, changes in magnetism were observed, which reported the hydrodynamic processes.
Subjects
1 H
bubble flow
chemical engineering
contrast agents
magnetic resonance imaging
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