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Item type:Publication, Access status: with files , Mullite photonic glasses with exceptional thermal stability for novel reflective thermal barrier coatings(Springer, 2023-08); ; ; ; Thermal barrier coatings are essential materials systems for insulating and protecting substrates exposed to high temperatures. In such systems, the heat transfer has three possible paths: conduction, convection and irradiation. The higher the operating temperature, the more important it is to control or protect against the radiative component, since the radiative heat flux becomes non-negligible. The radiation can be controlled by the use of ceramic-based photonic nanostructures, namely photonic crystals and photonic glasses, creating so-called reflective thermal barrier coatings. In this work, mullite inverse photonic glasses (PhG) have been produced by thermally induced reaction on sol–gel-based silica structures coated with nanometric films of Al2O3 by atomic layer deposition. The conversion to mullite was carried out following a two-stage heat-treatment. The pre-annealing associated with the further mullite formation results in an excellent structural stability of these PhGs up to 1500 °C, being able to retain their high reflectivity in the near infrared range. Therefore, this structure can be considered for next-generation reflective thermal barrier coatings. Graphical abstract: [Figure not available: see fulltext.]Publicationtype: Journal ArticleScopus© Citations 1 69 71 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: with files , Printing crack‐free microporous structures by combining additive manufacturing with colloidal assembly(Wiley-VCH, 2023-02); ; ; ; To date high printing resolution and scalability, i.e., macroscale component dimensions and fast printing, are incompatible characteristics for additive manufacturing (AM) processes. It is hereby demonstrated that the combination of direct writing as an AM process with colloidal assembly enables the breaching of this processing barrier. By tailoring printing parameters for polystyrene (PS) microparticle-templates, how to avoid coffee ring formation is demonstrated, thus printing uniform single lines and macroscale areas. Moreover, a novel “comb”-strategy is introduced to print macroscale, crack-free colloidal coatings with low viscous colloidal suspensions. The printed templates are transformed into ceramic microporous channels as well as photonic coatings via atomic layer deposition (ALD) and calcination. The obtained structures reveal promising wicking capabilities and broadband reflection in the near-infrared, respectively. This work provides guidelines for printing low viscous colloidal suspensions and highlights the advancements that this printing process offers toward novel applications of colloidal-based printed structures.Publicationtype: Journal ArticleScopus© Citations 2 89 207