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Item type:Publication, Access status: with files , Strength and ductility loss of Magnesium-Gadolinium due to corrosion in physiological environment: Experiments and modeling(Elsevier, 2023-08-01); ; ;Reinke, Inken; Luczak, MonikaWe propose a computational framework to study the effect of corrosion on the mechanical strength of magnesium (Mg) samples. Our work is motivated by the need to predict the residual strength of biomedical Mg implants after a given period of degradation in a physiological environment. To model corrosion, a mass-diffusion type model is used that accounts for localised corrosion using Weibull statistics. The overall mass loss is prescribed (e.g., based on experimental data). The mechanical behaviour of the Mg samples is modeled by a state-of-the-art Cazacu–Plunkett–Barlat plasticity model with a coupled damage model. This allowed us to study how Mg degradation in immersed samples reduces the mechanical strength over time. We performed a large number of in vitro corrosion experiments and mechanical tests to validate our computational framework. Our framework could predict both the experimentally observed loss of mechanical strength and the ductility due to corrosion for both tension and compression tests.Publicationtype: Journal ArticleScopus© Citations 2 44 104 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: without files , Barrel Finishing of Magnesium AlloysBarrel finishing is a well-established process in the industry for the targeted machining of surfaces. Especially small parts in large quantities with simple geometries can be easily machined this way. When investigating the biological behaviour of degradable magnesium implant alloys, platelets of 1 cm diameter and a thickness of slightly more than one mm are often used. Due to statistical requirements, a higher number of pieces are necessary. In addition, the geometry is comparatively simple. To ensure a certain reproducibility, all samples should also have comparatively similar surfaces. In this work, different abrasives and various process parameters are investigated to answer the question of whether barrel grinding is a viable process for producing reproducible specimens.Publicationtype: Conference Paper24 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: with files , Exploring key ionic interactions for magnesium degradation in simulated body fluid – a data-driven approach(Elsevier, 2021-01-22); ; ; ; We have studied the degradation of pure magnesium wire in simulated body fluid and its subsets under physiological conditions to enable the prediction of the degradation rate based on the medium's ionic composition. To this end, micro-computed tomography and scanning electron microscopy with energy-dispersive X-ray spectroscopy were used, followed by a tree regression analysis. A non-linear relationship was found between degradation rate and the precipitation of calcium salts. The mean absolute error for predicting the degradation rate was 1.35 mm/yr. This comparatively high value indicates that ionic interactions were exceedingly complex or that an unknown parameter determining the degradation may exist.Publicationtype: Journal ArticleScopus© Citations 22 193 359