Scalable fabrication and mechanical behaviour of hierarchical porous nickel networks

As the demand for light-weight structural and functional materials grows, the fabrication of hierarchical, high-performance micro- and nano-architectures becomes increasingly important. Here, we present a scalable alloying–dealloying strategy to fabricate porous metal with two- and three-level hierarchical networks (2 L-/3L-HN). By exploiting the vapour pressure difference between Ni and Zn, vapour phase alloying of Ni foam with Zn, followed by vapour phase dealloying of the resulting γ-Zn84Ni16 foam, generates a second hierarchical level, producing 2L-HN Ni or 2L-HN β-Zn50Ni50. Re-alloying 2L-HN β-Zn50Ni50 to 2L-HN γ-Zn84Ni16 via vapour phase alloying while preserving its hierarchical architecture enables chemical dealloying to create a third level of hierarchy at the nanoscale, producing 3L-HN Ni with significantly increased specific surface area. A novel scaling law is proposed to predict the mechanical properties of these hierarchical porous metallic networks as a function of solid fraction, and its validity is supported by compression tests on 2L-HN Ni with varying densities. This work establishes a scalable and versatile route for fabricating multiscale porous metallic networks with light-weight, tunable mechanical performance and high surface area.

Content

Subjects

Hierarchical nanoporous Ni

Mechanical properties

Metal foams

Vapour phase alloying

Vapour phase dealloying

DDC Class

620.1: Engineering Mechanics and Materials Science

Funding References

Funding(s)

EXC 3120 - BlueMat - Wassergesteuerte Materialien

Understanding ionic transports in dealloyed nanoporous metals

Files

Lizenz

https://creativecommons.org/licenses/by/4.0/

Publication version

publishedVersion

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1-s2.0-S0264127526016588-main-1.pdf

Type

Main Article

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6.18 MB

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Adobe PDF