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Item type:Publication, Access status: without files , Renormalized charge and dielectric effects in colloidal interactions: a numerical solution of the nonlinear Poisson–Boltzmann equation for unknown boundary conditions(Springer, 2023-09-11); ; ; Abstract: The Derjaguin–Landau–Verwey–Overbeek (DLVO) theory, introduced more than 70 years ago, is a hallmark of colloidal particle modeling. For highly charged particles in the dilute regime, it is often supplemented by Alexander’s prescription (Alexander et al. in J Chem Phys 80:5776, 1984) for using a renormalized charge. Here, we solve the problem of the interaction between two charged colloids at finite ionic strength, including dielectric mismatch effects, using an efficient numerical scheme to solve the nonlinear Poisson–Boltzmann (NPB) equation with unknown boundary conditions. Our results perfectly match the analytical predictions for the renormalized charge by Trizac and coworkers (Aubouy et al. in J Phys A 36:5835, 2003). Moreover, they allow us to reinterpret previous molecular dynamics (MD) simulation results by Kreer et al. (Phys Rev E 74:021401, 2006), rendering them now in agreement with the expected behavior. We furthermore find that the influence of polarization becomes important only when the Debye layers overlap significantly. Graphical Abstract: [Figure not available: see fulltext.].Publicationtype: Journal Article48 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: without files , Foam front propagation in anisotropic oil reservoirs(2016-04-01); ; ; ; Abstract.: The pressure-driven growth model is considered, describing the motion of a foam front through an oil reservoir during foam improved oil recovery, foam being formed as gas advances into an initially liquid-filled reservoir. In the model, the foam front is represented by a set of so-called “material points” that track the advance of gas into the liquid-filled region. According to the model, the shape of the foam front is prone to develop concave sharply curved concavities, where the orientation of the front changes rapidly over a small spatial distance: these are referred to as “concave corners”. These concave corners need to be propagated differently from the material points on the foam front itself. Typically the corner must move faster than those material points, otherwise spurious numerical artifacts develop in the computed shape of the front. A propagation rule or “speed up” rule is derived for the concave corners, which is shown to be sensitive to the level of anisotropy in the permeability of the reservoir and also sensitive to the orientation of the corners themselves. In particular if a corner in an anisotropic reservoir were to be propagated according to an isotropic speed up rule, this might not be sufficient to suppress spurious numerical artifacts, at least for certain orientations of the corner. On the other hand, systems that are both heterogeneous and anisotropic tend to be well behaved numerically, regardless of whether one uses the isotropic or anisotropic speed up rule for corners. This comes about because, in the heterogeneous and anisotropic case, the orientation of the corner is such that the “correct” anisotropic speed is just very slightly less than the “incorrect” isotropic one. The anisotropic rule does however manage to keep the corner very slightly sharper than the isotropic rule does. Graphical abstract: [Figure not available: see fulltext.]Publicationtype: Journal ArticleScopus© Citations 11 21 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: without files , Foam-improved oil recovery: Modelling the effect of an increase in injection pressure(2015-06-01); ; Abstract: A model, called pressure-driven growth, is analysed for propagation of a foam front through an oil reservoir during improved oil recovery using foam. Numerical simulations of the model predict, not only the distance over which the foam front propagates, but also the instantaneous front shape. A particular case is studied here in which the pressure used to drive the foam along is suddenly increased at a certain point in time. This transiently produces a concave front shape (seen from the domain ahead of the front): such concavities are known to be delicate to handle numerically. As time proceeds however, the front evolves back towards a convex shape, and this can be predicted by a long-time asymptotic analysis of the model. The increase in driving pressure is shown to be beneficial to the improved oil recovery process, because it gives a more uniform sweep of the oil reservoir by the foam. Graphical abstract: [Figure not available: see fulltext.]Publicationtype: Journal Article22 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: without files , Rich polymorphism of a rod-like liquid crystal (8CB) confined in two types of unidirectional nanopores(Springer, 2008-05-29); ; ; ; We present a neutron and X-rays scattering study of the phase transitions of 4-n-octyl-4' -cyanobiphenyl (8CB) confined in unidirectional nanopores of porous alumina and porous silicon (PSi) membranes with an average diameter of 30nm. Spatial confinement reveals a rich polymorphism, with at least four different low temperature phases in addition to the smectic A phase. The structural study as a function of thermal treatments and conditions of spatial confinement allows us to get insights into the formation of these phases and their relative stability. It gives the first description of the complete phase behavior of 8CB confined in PSi and provides a direct comparison with results obtained in bulk conditions and in similar geometric conditions of confinement but with reduced quenched disorder effects using alumina anopore membranes.Publicationtype: Journal ArticleScopus© Citations 36 14 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Access status: without files , Are solidified fillings of mesopores basically bulk-like except for the geometric confinement?(Springer, 2003-09-01); ; ; ; A short review of our thermodynamic and structural work on Ar, N 2, CO, O2, and the n-alkane C19H40 in mesoporous glasses is presented. The experimental information comes from X-ray diffraction, vapour pressure isotherms, optical transmission, heat capacity, and dielectric measurements. The filling in the pore centre formed by capillary condensation is distinguished from the adsorbed layers on the pore walls and is compared to the bulk state. Special attention is paid to metastable states and to the rearrangement of partial fillings that show up as a consequence of phase transitions.Publicationtype: Conference Paper15