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    Item type:Publication, Access status: with files ,
    Impact of powdered activated carbon and anion exchange resin on photocatalytic treatment of textile wastewater
    (Scientific Research Publishing (SCIRP), 2015-03-05) ; ;
    In order to clarify the impact of activated carbon and anion exchange resin on photocatalytic oxidation (PCO) of textile industry wastewater, TiO2-based PCO was investigated with aqueous solutions containing the reactive dye Reactive Blue 4 (RB4) and with a textile dye house effluent in the absence and in the presence of powdered activated carbon (PAC) and the anion exchange resin Lewatit MP 500. Addition of Lewatit improved RB4 removal to a larger extent than PAC addition. Contrasting to chloride and sulfate, hydrogen carbonate clearly inhibited PCO of RB4. However, the depression of dye removal by hydrogen carbonate was minute in the presence of Lewatit although the hydrogen carbonate concentration was not markedly decreased. Unfortunately, the beneficial effect of Lewatit addition on PCO nearly disappeared when the Lewatit/TiO2 mixture was reused three times. This was probably caused by oxidative damage of the resin. Color removal from the real dye house effluent during PCO was improved by Lewatit, but not by PAC. Contrastingly, PAC addition increased TOC removal by PCO from the real wastewater to some extent, while Lewatit had no impact. Sorbent addition does not lead to an acceptable area demand for solar PCO of the dye house effluent.
    Publicationtype: Journal Article
      908  597
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    Item type:Publication, Access status: with files ,
    Pretreating stored human urine for solar evaporation by low-technology ammonia stripping
    (Scientific Research Publishing (SCIRP), 2014-08-22) ; ;
    In order to avoid the loss of ammonia during solar drying of stored urine, low-tech stripping is suggested as a pretreatment process for ammonia recovery. The mass transfer of ammonia from stored urine with an initial pH of about 9 was tested in a simple closed vessel operated at 72˚C, 74˚C and 85˚C. The specific urine/gas interface was 16.97 m−1. For ammonia absorption, a beaker with sulfuric acid was positioned in the gas phase of the container. After keeping the stored urine for 73 h at 85˚C, the concentration of free ammonia (NH3) was reduced by more than 99%, and the pH of the stored urine decreased to 6.4 due to ammonia volatilization. Total ammonia (NH3 + NH4+) concentration was reduced by only 83% in the same period. At lower temperatures, the process was slower. Required treatment time can be reduced when specific gas/liquid interface is increased. Because it is known that water can be heated in solar boxes to temperatures above 90˚C, this simple stripping apparatus is feasible to be operated with solar energy in remote areas with suitable climatic conditions where no electric power is available. As the area demand for solar “low-tech stripping” is less than 1 m2 per capita, this process can be looked at as a suitable pretreatment of stored urine prior to solar evaporation.
    Publicationtype: Journal Article
      696  962